Baeyer-Villiger Reaction of Benzaldehydes Possessing Oxygen Functions with SeO2-H2O2

Autor:	Keiko Katsuno, Masako Fujii, Takashi Harayama, Yoshitaka Nishita, Hiromi Nishioka, Natsuko Koshiba
Rok vydání:	1999
Předmět:	Pharmacology chemistry.chemical_classification Pharmaceutical Science chemistry.chemical_element Ring (chemistry) Formyl group Medicinal chemistry Aldehyde Oxygen Para position chemistry.chemical_compound chemistry Yield (chemistry) Furan Organic chemistry
Zdroj:	YAKUGAKU ZASSHI. 119:519-528
ISSN:	1347-5231 0031-6903
DOI:	10.1248/yakushi1947.119.7_519
Popis:	The Baeyer-Villiger (B. V.) reaction using SeO2-H2O2 was examined for various benzaldehydes possessing methoxy groups and/or a furan ring. When benzaldehydes have an electron-donating group (methoxy group) at the ortho or para position to a formyl group, the B. V. reaction proceeded rapidly and in a good yield. Since the reaction using SeO2-H2O2 is carried out under a neutral condition, this reaction are applicable to aldehyde derivatives with a furan ring which is unstable against acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb2e0036b6102bddfc5e1a2800a6b06e https://doi.org/10.1248/yakushi1947.119.7_519 Zobrazit plný text záznamu