Metal templated receptors for the effective complexation of dicarboxylates
Autor: | M. Scott Goodman, Andrew D. Hamilton, Vrej Jubian |
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Rok vydání: | 1995 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 36:2551-2554 |
ISSN: | 0040-4039 |
DOI: | 10.1016/0040-4039(95)00337-c |
Popis: | In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by 1 H NMR in DMSO and association constants of >10 4 M −1 were measured in certain cases. |
Databáze: | OpenAIRE |
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