Metal templated receptors for the effective complexation of dicarboxylates

Autor: M. Scott Goodman, Andrew D. Hamilton, Vrej Jubian
Rok vydání: 1995
Předmět:
Zdroj: Tetrahedron Letters. 36:2551-2554
ISSN: 0040-4039
DOI: 10.1016/0040-4039(95)00337-c
Popis: In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by 1 H NMR in DMSO and association constants of >10 4 M −1 were measured in certain cases.
Databáze: OpenAIRE