Mechanism of protective action of operational-preservative oils

Autor:	I. F. Blagovidov, L. G. Rappeport, V. S. Demchenko, V. S. Luneva
Rok vydání:	1971
Předmět:	Preservative Moisture Chemistry General Chemical Engineering Slow rate Energy Engineering and Power Technology General Chemistry Metal Fuel Technology Adsorption Chemical engineering Chemisorption visual_art visual_art.visual_art_medium Organic chemistry Layer (electronics) Deposition (law)
Zdroj:	Chemistry and Technology of Fuels and Oils. 7:863-866
ISSN:	1573-8310 0009-3092
DOI:	10.1007/bf00717099
Popis:	1. The film formed by oils containing the KP additive consists of several layers. The layer adjacent to the metal is attached by chemisorption bonds, which are formed at a rather slow rate. The remaining layers are bonded by primary adsorption forces. 2. The protective effect of oils with the KP additive is manifested within 5 to 10 min after deposition on the metal, owing to a change in the structure of the electrical double layer of the metal, caused by adsorption of the surfactants of the additive at the metal surface. 3. When in contact with moisture, oils with KP additive absorb water, forming a water-in-oil system, so that the water does not pass through the oil to the metal surface. 4. The KP additive should be added to oils in amounts of 10–20%.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb17c175e0663d8e61b2e6b131cde1e4 https://doi.org/10.1007/bf00717099 Zobrazit plný text záznamu Full text from SpringerLink