Enrichment of lithium isotope 6Li by ion exchange resin with specific particle size
| Autor: | L. Jelínek, J. Ďurišová, J. Mikeš |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Ion exchange
010405 organic chemistry Health Toxicology and Mutagenesis Ammonium nitrate Isotopes of lithium Ion chromatography Public Health Environmental and Occupational Health Analytical chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Pollution Displacement chromatography 0104 chemical sciences Analytical Chemistry Isotope separation law.invention chemistry.chemical_compound Nuclear Energy and Engineering chemistry law Radiology Nuclear Medicine and imaging Lithium Particle size Spectroscopy |
| Zdroj: | Journal of Radioanalytical and Nuclear Chemistry. 312:13-18 |
| ISSN: | 1588-2780 0236-5731 |
| DOI: | 10.1007/s10967-017-5198-x |
| Popis: | Enrichment of lithium isotopes by displacement chromatography on strong acid cation exchanger was investigated. Narrow particle fraction of Dowex 50 WX 2 cation exchanger having diameter of 150–200 µm and total exchange capacity of 1.31 meq mL−1 was used as stationary phase. As a mobile phase, 1 mol L−1 solution of ammonium nitrate solution was used. Shape and position of Li chromatographic peak, was determined by atomic emission spectroscopy (AES). Isotope ratio was estimated by ICP–MS after 1, 8 and 10 enrichment steps. Value of separation factor for 6Li in one step was determined to be 1.027. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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