An Influence of Nano-Sized Fillers Fe3O4, ZnO on the Thermal Oxidation Resistance of Inhibited Polyethylene

Autor:	E. V. Vorobyova
Rok vydání:	2021
Předmět:	chemistry.chemical_classification Thermal oxidation Nanocomposite General Chemical Engineering Composite number Oxide Nanoparticle General Chemistry Polymer Polyethylene Metal chemistry.chemical_compound chemistry Chemical engineering visual_art visual_art.visual_art_medium
Zdroj:	Russian Journal of Applied Chemistry. 94:1066-1071
ISSN:	1608-3296 1070-4272
Popis:	The effect of fillers, metal oxide nanoparticles (Fe3O4, ZnO), on the thermal oxidation resistance of polyethylene inhibited by the phenolic antioxidant Irganox 1010 was studied. The distribution of nanoparticles in the polymer matrix was carried out by ultrasound, and the samples were formed by thermal pressing. Thermal oxidation resistance was determined by the duration of the induction oxidation period of film samples. It is shown that the pressure of the press during the formation of the material has a significant effect on the thermal oxidation resistance of the inhibited composite, both filled with nanoparticles of Fe3O4, ZnO, and unfilled. The nature of the effect of the concentration of the nanofiller on the thermal oxidation resistance of the samples depends on the metal oxide used. An increase in the concentration of the filler Fe3O4 leads to a decrease in the thermal oxidation resistance of the polymer; when using ZnO, this dependence is inverse. The oxidation of the prepared nanocomposite film samples formed under high pressure conditions revealed synergistic effects of nanofillers and antioxidants.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb0df6267b82dba837fb1cbfa060eb06 https://doi.org/10.1134/s1070427221080073 Zobrazit plný text záznamu Full text from SpringerLink