Siliranes: Formation, isonitrile insertions, and thermal rearrangements

Autor:	Wolfang Saak, Siegfried Pohl, Stefan Willms, Heinrich Marsmann, Edwin Kroke, Manfred Weidenbruch
Rok vydání:	1996
Předmět:	chemistry.chemical_compound Chemistry Organic Chemistry Drug Discovery Polymer chemistry Thermal decomposition Silylene Biochemistry
Zdroj:	Tetrahedron Letters. 37:3675-3678
ISSN:	0040-4039
Popis:	The siliranes 7–10 and 22 as well as the vinylsiliranes 14–16, 20 , and 21 are prepared by [1+2]-cycloadditions of silylene 2 with alkenes and dienes. The first isonitrile insertion products, the silacyclobutanimines 26–28 were synthesized and the structure of 28 was determined by X-ray crystallography. Upon thermolysis 20–22 rearranged quantitatively to furnish the compounds 29–32 .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eb08d0d73e3d8a4ab4cc5b391f9f9a4c https://doi.org/10.1016/0040-4039(96)00650-8 Zobrazit plný text záznamu Full Text from ScienceDirect