Magnetic Interaction between d1 [MOR4]− Units of Molybdenum and Tungsten
| Autor: | Miguel Baya, Conrado Rillo, Babil Menjón, M. Angeles García-Monforte, Ana B. Arauzo, Fernando Luis, Pablo J. Alonso, Antonio Martín |
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| Rok vydání: | 2016 |
| Předmět: |
Materials science
Inorganic chemistry chemistry.chemical_element Tungsten Condensed Matter Physics Atomic and Molecular Physics and Optics law.invention Crystal Crystallography Ferromagnetism chemistry Group (periodic table) Molybdenum law General Materials Science Magnetic interaction Electron paramagnetic resonance |
| Zdroj: | Solid State Phenomena. 257:223-226 |
| ISSN: | 1662-9779 |
| Popis: | Five-coordinate oxo-derivatives [NBu4][MO(C6F5)4] (1) have been prepared for the heavier Group 6 elements: 1-Mo and 1-W. The magnetic properties of that salts have been studied by a combination of Electron paramagnetic resonance (EPR), calorimetric and magnetochemical techniques, pointing out the existence of weak ferromagnetic interactions. These have been correlated with the arrangement of the magnetic units in the crystal. |
| Databáze: | OpenAIRE |
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