Synthesis of Highly Insulated Molecular Wires by Polymerization of Organic-Soluble Symmetrical Linked Inclusion Complex Monomers

Autor:	Nobuaki Kambe, Susumu Tsuda, Keisuke Tsurui, Jun Terao
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Photoluminescence Materials science Polymers and Plastics Cyclodextrin Organic Chemistry Condensed Matter Physics Fluorescence chemistry.chemical_compound Molecular wire Monomer chemistry Polymerization Polymer chemistry Materials Chemistry Inclusion (mineral) Glaser coupling
Zdroj:	Macromolecular Symposia. 297:54-60
ISSN:	1022-1360
DOI:	10.1002/masy.200900053
Popis:	We developed a new method for synthesizing an organic-soluble per-methylated cyclodextrin-based insulated molecular wire (IMW); this method involves the polymerization of a symmetrical linked inclusion complex as a monomer. This monomer was synthesized by dimerization of linked inclusion complexes at the terminal alkynyl groups by Glaser coupling. The polyrotaxane thus obtained is highly soluble in a variety of organic solvents and has a high covering ratio, regioregularity, and photoluminescence efficiency.
Databáze:	OpenAIRE
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