Electron attachment processes in halomethanes

Autor: I. Szamrej
Rok vydání: 1998
Předmět:
Zdroj: Journal of Radioanalytical and Nuclear Chemistry. 232:63-66
ISSN: 1588-2780
0236-5731
DOI: 10.1007/bf02383713
Popis: We have investigated thermal electron capture processes in the mixtures of halomethanes and carbon dioxide (in excess) using the electron swarm method. We have found that except the very slow second order reactions (single collision) there occur processes involving homo-(RX)2 or heterogeniouos (RX·CO2) van der Waals complexes (multi-body pressure dependent processes) which are at least a few times faster at atmospheric pressures. The mechanism and the kinetics of some of these processes are presented.
Databáze: OpenAIRE