Electron attachment processes in halomethanes
Autor: | I. Szamrej |
---|---|
Rok vydání: | 1998 |
Předmět: |
Health
Toxicology and Mutagenesis Kinetics Public Health Environmental and Occupational Health Pressure dependent Electron Pollution Analytical Chemistry chemistry.chemical_compound symbols.namesake Thermal electron Nuclear Energy and Engineering chemistry Chemical physics Carbon dioxide symbols Electron attachment Radiology Nuclear Medicine and imaging Atomic physics van der Waals force Spectroscopy |
Zdroj: | Journal of Radioanalytical and Nuclear Chemistry. 232:63-66 |
ISSN: | 1588-2780 0236-5731 |
DOI: | 10.1007/bf02383713 |
Popis: | We have investigated thermal electron capture processes in the mixtures of halomethanes and carbon dioxide (in excess) using the electron swarm method. We have found that except the very slow second order reactions (single collision) there occur processes involving homo-(RX)2 or heterogeniouos (RX·CO2) van der Waals complexes (multi-body pressure dependent processes) which are at least a few times faster at atmospheric pressures. The mechanism and the kinetics of some of these processes are presented. |
Databáze: | OpenAIRE |
Externí odkaz: |