Homogeneous hydrogenation and deuteration of pentacyclic triterpenoids: Double bonds in side-chains

Autor:	Jiří Klinot, Alois Vystrčil, Luděk Lepša, Jiří Protiva, Václav Křeček, Eva Klinotová
Rok vydání:	1981
Předmět:	chemistry.chemical_classification Double bond chemistry Stereochemistry Homogeneous Polymer chemistry Side chain Pentacyclic triterpenoids General Chemistry
Zdroj:	Collection of Czechoslovak Chemical Communications. 46:2734-2741
ISSN:	1212-6950 0010-0765
DOI:	10.1135/cccc19812734
Popis:	The reduction of terminal double bonds in the side chains on the rings A and E of pentacyclic triterpenoids by means of tris(triphenylphosphine)rhodium chloride permits selective reduction of dienes and labelling with deuterium with a low scattering. The effect of the amount of the catalyst and the solvent used on the rate of reduction was studied in the case of 3β,28-diacetylbetulin.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::eab9da92ff565c03f9e32613e32a996b https://doi.org/10.1135/cccc19812734 Zobrazit plný text záznamu