Palladium decorated porous nickel having enhanced electrocatalytic performance for hydrazine oxidation
| Autor: | He Wen, Ping Wang, Xiao-Ping Wen, Lin-Song Wu, Hong-Bin Dai |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Hydrazine Energy Engineering and Power Technology chemistry.chemical_element 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Electrocatalyst 01 natural sciences 0104 chemical sciences Catalysis Nickel chemistry.chemical_compound chemistry Chemical engineering Galvanic cell Electrical and Electronic Engineering Physical and Theoretical Chemistry 0210 nano-technology Porosity Palladium |
| Zdroj: | Journal of Power Sources. 412:71-77 |
| ISSN: | 0378-7753 |
| DOI: | 10.1016/j.jpowsour.2018.11.023 |
| Popis: | Crucial to enabling hydrous hydrazine as a viable fuel is the development of high-performance electrocatalysts. Herein, we report the synthesis of a palladium decorated porous nickel electrocatalyst using a combination of the dealloying and galvanic replacement methods. The obtained electrocatalyst shows outstanding catalytic activity and good long-term durability towards hydrazine oxidation. The mechanistic reason for the improved electrocatalytic performance is discussed based on the structural characterization and controlled experiments. Our study demonstrates that the electrocatalytic properties of catalyst can be improved by enhancing the number of active sites and its intrinsic activity. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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