X-Ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands ‡

Autor:	Catherine M. McGrath, David Collison, Nigel A. Young, John F. Walsh, C. David Garner, Julian Grigg, Geoff Thornton, J. Frederick W. Mosselmans, M. D. Roper, Jon M. W. Seddon, Peter A. Tasker, Ekk Sinn, Elna Pidcock
Rok vydání:	1998
Předmět:	chemistry.chemical_compound Crystallography Monomer chemistry Atomic electron transition Bound state Vanadium chemistry.chemical_element General Chemistry Low symmetry Spectral line X-ray absorption fine structure
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :2199-2204
ISSN:	1364-5447 0300-9246
Popis:	A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V–N–O–V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N–O groups.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ea9b69e957a0139f9d192894e2d2e4be https://doi.org/10.1039/a800568k Zobrazit plný text záznamu