A simple and facile to prepare Pd(II) complex containing the pyridyl imine ligand [C5H4N-2-CH3CN-(CH2)3NH2]. Structural characterization and catalytic evaluation in Suzuki–Miyaura C–C couplings
| Autor: | Patricia Conelly-Espinosa, David Morales-Morales, Rubén A. Toscano, Juan Manuel Germán-Acacio, Oscar Baldovino-Pantaleón, Reyna Reyes-Martínez, Alcives Avila-Sorrosa, J. Roberto Pioquinto-Mendoza |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
chemistry.chemical_classification
Ligand Chemistry Stereochemistry Organic Chemistry Imine Crystal structure Biochemistry Catalysis Characterization (materials science) Inorganic Chemistry chemistry.chemical_compound Polymer chemistry Materials Chemistry Non-covalent interactions Molecule Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Journal of Organometallic Chemistry. 797:153-158 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/j.jorganchem.2015.08.024 |
| Popis: | The facile and simple synthesis and structural characterization of a Pd(II) complex derived from the ligand N1-(1-(pyridin-2-yl)ethylidene)propane-1,3-diamine (L1) is described. The Pd(II) species [Pd(L1)Cl][BF4] (PdL1) has been fully characterized and its structure unequivocally determined by single crystal X-ray diffraction techniques. The molecular structure of PdL1 shows the ligand L1 coordinated in a κ3-N,N,N-tridentate fashion thus affording a slightly distorted square planar compound. This species was employed as catalyst in Suzuki–Miyaura couplings affording good to excellent yields. Furthermore, in the solid state this compound exhibited extended hydrogen-bond networks. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect