Thermolysis of potassium tetraperoxochromate(V)

Autor:	Sergei V. Levchik, A. I. Lesnikovich, K.K. Kovalenko
Rok vydání:	1986
Předmět:	Rate regulation Thermal decomposition Kinetics Inorganic chemistry Thermodynamics Potassium tetraperoxochromate(V) Condensed Matter Physics Kinetic energy Decomposition External pressure chemistry.chemical_compound chemistry Physical and Theoretical Chemistry Instrumentation Pyrolysis
Zdroj:	Thermochimica Acta. 102:293-302
ISSN:	0040-6031
DOI:	10.1016/0040-6031(86)85338-2
Popis:	The dependence of the rate of self-propagating high-temperature decomposition (SHD) on several variable factors may be approximated by a polylinear function. The applicability and predictability of the polylinear expansion of the rate of K 3 CrO 8 SHD as a function of external pressure and activity of additives are shown. The limits of the K 3 CrO 8 SHD rate regulation due to additives are specified. Invariant values of the kinetic parameters of decomposition of the mixtures based on K 3 CrO 8 are estimated. The mechanism of the effect of different additives on K 3 CrO 8 SHD is discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ea878ed523cb885405707319c0197b37 https://doi.org/10.1016/0040-6031(86)85338-2 Zobrazit plný text záznamu