ChemInform Abstract: Oxidative Cross-Coupling of Vinylsilanes in Water

Autor: Stefania R. Cicco, Francesco Naso, Vita Pinto, Carmela Martinelli, Gianluca M. Farinola
Rok vydání: 2013
Předmět:
Zdroj: ChemInform. 44
ISSN: 0931-7597
DOI: 10.1002/chin.201335048
Popis: Palladium-promoted cross-dimerization reaction of alkenylsilanes is reported for the first time, which is also one of the very first studies on oxidative cross-coupling between vinylic organometallic reagents. The reaction occurs at room temperature in aqueous micelles and represents a convenient access to all-trans push–pull butadienes.
Databáze: OpenAIRE