Extraction of Actinides from a Chloride Medium Using Pentaalkylpropanediamides
Autor: | Claude Musikas, Christine Cuillerdier |
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Rok vydání: | 1993 |
Předmět: |
Process Chemistry and Technology
General Chemical Engineering Extraction (chemistry) Inorganic chemistry food and beverages chemistry.chemical_element Filtration and Separation Americium Hydrochloric acid General Chemistry Ascorbic acid Diluent Chloride Plutonium chemistry.chemical_compound chemistry Pyrometallurgy medicine Nuclear chemistry medicine.drug |
Zdroj: | Separation Science and Technology. 28:115-126 |
ISSN: | 1520-5754 0149-6395 |
DOI: | 10.1080/01496399308019481 |
Popis: | Pyrometallurgical processes for the purification of plutonium for defense create waste solutions containing actinides, mainly americium, in chloride medium. Studies have been undertaken to study the extraction of actinides in a chloride medium (hydrochloric acid mixed with concentrated salts such as LiCl, CaCl2, MgCl2, KCl) using pentaalkylpropanediamides as extractants. Plutonium(IV) is very easily extracted, but Am(III) needs a salting-out agent such as LiCl. Back extraction of trivalent cations is easy in HCl |
Databáze: | OpenAIRE |
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