Investigation of structure of GeS1.35 glasses with the use of isotopically enriched germanium and Raman scattering spectroscopy
| Autor: | Yu. S. Tver’yanovich, М.F. Churbanov, D.V. Pan'kin, М.V. Sukhanov |
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| Rok vydání: | 2017 |
| Předmět: |
Materials science
Analytical chemistry chemistry.chemical_element Germanium 02 engineering and technology Raman scattering spectroscopy Condensed Matter::Disordered Systems and Neural Networks 01 natural sciences Spectral line symbols.namesake 0103 physical sciences Materials Chemistry Nuclear Experiment 010302 applied physics 021001 nanoscience & nanotechnology Condensed Matter Physics Sulfur Isotopic composition Atomic mass Electronic Optical and Magnetic Materials chemistry Molecular vibration Ceramics and Composites symbols 0210 nano-technology Raman scattering |
| Zdroj: | Journal of Non-Crystalline Solids. 457:164-168 |
| ISSN: | 0022-3093 |
| DOI: | 10.1016/j.jnoncrysol.2016.11.038 |
| Popis: | The samples of GeS 1.35 glasses were synthesized with germanium and sulfur of natural isotopic composition and with isotopically enriched germanium ( 72 Ge, 74 Ge, 76 Ge). The glasses were investigated by the method of Raman scattering spectroscopy (RSS). It was shown that GeS 4/2 tetrahedrons and structural units containing Ge Ge homobonds are present in glasses. The quantum-mechanical calculation of the frequency of fundamental vibrational modes in glass network was carried out. Their dependencies on the atomic mass of germanium were used for identification of bands in RS (Raman scattering) spectra. |
| Databáze: | OpenAIRE |
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