Rotation model of the diffusion mobility of macromolecules in linear polymer crystallites

Autor:	Ulmas Gafurov
Rok vydání:	1999
Předmět:	Condensed Matter::Soft Condensed Matter chemistry.chemical_classification Quantitative Biology::Biomolecules Self-diffusion Condensed matter physics Chemistry Intermolecular force Degrees of freedom (physics and chemistry) Polymer Crystallite Deformation (meteorology) Rotation Potential energy
Zdroj:	SPIE Proceedings.
ISSN:	0277-786X
DOI:	10.1117/12.347421
Popis:	The rotational model of kink, which can explain the rotation mobility and self-diffusion of linear macromolecules in the crystallites of flexible chain polymers has been proposed. We take into account both the rotation of molecular groups and the deformation of chains in the intermolecular field. The potential energy of kink-like deformation has been found when a chain described by two groups of degrees of freedom.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::ea33cdc02b47859756fd70f47b45e738 https://doi.org/10.1117/12.347421 Zobrazit plný text záznamu