Tetramethylthiuram Monosulfide and Tetramethylthiuram Disulfide: Heats of Formation and the S—S Thermochemical Bond Energy

Autor:	W. D. Good, J. P. McCullough, J. L. Lacina
Rok vydání:	1962
Předmět:	Alkane chemistry.chemical_classification Polymers and Plastics Sulfide Inorganic chemistry chemistry.chemical_element Calorimetry Combustion Nitrogen Sulfur Standard enthalpy of formation chemistry Materials Chemistry Bond energy
Zdroj:	Rubber Chemistry and Technology. 35:661-664
ISSN:	1943-4804 0035-9475
DOI:	10.5254/1.3539943
Popis:	The heats of combustion and formation were determined for tetramethylthiuram monosulfide [bis-(dimethylthiocarbamoyl) sulfide] and tetramethylthiuram disulfide [bis-(dimethylthiocarbamoyl) disulfide]. The S—S thermochemical bond energy in tetramethylthiuram disulfide was shown to be about the same as in normal alkane disulfides and in S8. Rotating-bomb combustion calorimetry was found satisfactory for compounds that contain both sulfur and nitrogen.
Databáze:	OpenAIRE
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