ChemInform Abstract: N-Methylpyrrolidone Hydroperoxide/Cs2CO3as an Excellent Reagent System for the Hydroxy-Directed Diastereoselective Epoxidation of Electron-Deficient Olefins

Autor: Napoleon John Victor, K. M. Muraleedharan, Janardhanan Gana
Rok vydání: 2016
Předmět:
Zdroj: ChemInform. 47
ISSN: 0931-7597
DOI: 10.1002/chin.201611122
Popis: The title reagent system is efficiently used for the chemoselective epoxidation of various hydroxy group-containing electron deficient olefins, and the reaction is shown to proceed diastereoselectively if an unprotected hydroxy group is present and non-diastereoselectively in case of protected analogues.
Databáze: OpenAIRE