Development of supramolecular structure through alkylation of pendant pyridyl functionality

Autor:	Yves C. Zimmermann, David Phillips, Emma Sparr, Edwin C. Constable, Derek A. Tocher, Margareta Zehnder, Catherine E. Housecroft, Markus Neuburger, Paul R. Raithby, Emma R. Schofield
Rok vydání:	2000
Předmět:	Molecular recognition Chemistry Ligand Stereochemistry Supramolecular chemistry General Chemistry Alkylation Combinatorial chemistry
Zdroj:	Journal of the Chemical Society, Dalton Transactions. :2219-2228
ISSN:	1364-5447 1470-479X
DOI:	10.1039/b000940g
Popis:	The complex 12+ which has two pendant 4-pyridyl substituents may be viewed as a metal-containing analogue of 4,4′-bipyridine. The complex undergoes N-alkylation reactions with a variety of alkylating agents to give more highly functionalised tetracationic complexes which may be termed metalloviologens by analogy with viologens. These complexes may also be prepared by alkylation of the free ligands and subsequent coordination of the pendant quaternised ligand. Structural studies have established that the N-alkylated complexes possess the correct spatial characteristics for the preparation of metallocycles analogous to known cyclic bis(4,4′-bipyridinium) species which possess useful molecular recognition properties.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e9c8d65dc5767de4368459c61bdd7671 https://doi.org/10.1039/b000940g Zobrazit plný text záznamu