A New One Dimensional Mn(III) Coordination Polymer Constructed by a Salicylamide Imine Multidentate Ligand: Structure, Magnetic and Luminescent Properties
| Autor: | Zen-Gang Lin, Xue-Li Xia, Xue-Qin Song, Huan-Huan Meng |
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| Rok vydání: | 2019 |
| Předmět: |
Denticity
Materials science Polymers and Plastics Coordination polymer Ligand Imine 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Crystallography Deprotonation chemistry Amide Materials Chemistry Antiferromagnetism 0210 nano-technology Single crystal |
| Zdroj: | Journal of Inorganic and Organometallic Polymers and Materials. 29:1995-2002 |
| ISSN: | 1574-1451 1574-1443 |
| DOI: | 10.1007/s10904-019-01158-4 |
| Popis: | A new Mn(III) coordination polymer, [MnL]n, based on a salicylamide imine multidentate ligand, 1-(2-hydroxy-benzamido)-2-(2-hydroxy-5-nitrobenzylideneamino)-ethane (H3L) was prepared. Single crystal analysis revealed that the title compound was a herringbone like Mn(III) coordination polymer where deprotonated ligand L3– acted as a pentadentate ligand with amide group being bridge to connect two Mn(III) centres. Magnetic susceptibilities indicates that [MnL]n exhibits an antiferromagnetic coupling with a long-range canted antiferromagnetic ordering and metamagnetic behavior at low temperatures. And the photophysical determination shows that [MnL]n also displays strong long life red luminescence. The results presented herein indicates [MnL]n appears to be an excellent candidate for multifunctional material as a result of its high thermal stability, interesting magnetic and luminescent properties. |
| Databáze: | OpenAIRE |
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