Fluorescence, optical absorption and third-order nonlinear optical properties of terbium (III) complex embedded into DNA-CTMA matrix
| Autor: | Cosmina Andreea Lazar, Ana-Maria Manea, Francois Kajzar, Ileana Rau |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Spin coating
Photoluminescence Materials science Biophysics Analytical chemistry chemistry.chemical_element Terbium 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences Biochemistry Fluorescence Atomic and Molecular Physics and Optics 0104 chemical sciences Bipyridine chemistry.chemical_compound chemistry Molecule Thin film Absorption (chemistry) 0210 nano-technology |
| Zdroj: | Journal of Luminescence. 182:59-64 |
| ISSN: | 0022-2313 |
| DOI: | 10.1016/j.jlumin.2016.10.010 |
| Popis: | New DNA based materials, functionalized with hexadecyltrimethylammonium chloride (CTMA) and terbium – bis – (2.2′ – bipyridine) triazotate molecules [Tb(NO 3 ) 3 (bpy) 2 ], were prepared. The obtained complexes were processed into good optical quality thin films by spin coating method on commercial glass substrates and characterized for their spectroscopic, linear and nonlinear optical properties. The solution absorption and fluorescence measurements show incorporation of Tb(NO 3 ) 3 (bpy) 2 into DNA-CTMA backbones. Furthermore, the photoluminescent properties of the DNA-CTMA/Tb(NO 3 ) 3 (bpy) 2 thin films were superior to that of DNA-CTMA/Tb(NO 3 ) 3 (bpy) 2 solutions. The third-order nonlinear optical (NLO) properties of thin films were determined by the optical third-harmonic generation technique at 1 064.2 nm fundamental wavelength. A large cubic susceptibility of Tb complex is observed. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect