Dynamics of HD Molecules Trapped in Cages of Zeolite

Autor: Yu Ji, J. A. Hamida, Neil Sullivan
Rok vydání: 2010
Předmět:
Zdroj: Journal of Low Temperature Physics. 162:121-126
ISSN: 1573-7357
0022-2291
DOI: 10.1007/s10909-010-0250-z
Popis: There is considerable interest in the use of mesoporous structures (e.g. zeolites and metal organic frameworks) for hydrogen storage but little is known about the molecular interactions and the dynamics of molecules inside the cages of these structures. In order to determine these properties we have measured the nuclear magnetic spin-lattice and spin-spin relaxation times of HD molecules trapped in the α-cages of zeolite 13X for a wide temperature range 1.6 12 K, corresponding to the onset of intercage diffusion.
Databáze: OpenAIRE