Obtaining dimethylalkylamines from CO, H2 and (CH3)2NH by the modified Fischer-Tropsch synthesis on a reduced fused magnetite catalyst: molecular weight distribution of the products and synthesis mechanism

Autor:	Popova Tamara P, O.A. Lesik, Glebov Leonid S, V. P. Ryzhikov, V.G. Beryezkin, V. E. Shiryaeva, G. A. Kliger, S. M. Loktev, E. V. Marchevskaya
Rok vydání:	1986
Předmět:	chemistry.chemical_classification chemistry.chemical_compound Ketone chemistry Tertiary amine Alkene General Engineering Organic chemistry Molar mass distribution Fischer–Tropsch process Aliphatic compound Dimethylamine Catalysis
Zdroj:	Journal of Molecular Catalysis. 35:335-348
ISSN:	0304-5102
DOI:	10.1016/0304-5102(86)87081-x
Popis:	The composition of the synthesis products obtained from CO, H2 and dimethylamine on a reduced fused magnetite catalyst has been studied. The molecular weight distribution of all the identified product components has been found to adhere to the Schulz-Flory equation. Alkanes have been shown to have a distribution coefficient α different from that for olefins, alcohols, ketones and dimethylalkylamines (DMAA). A mechanism of the modified Fischer-Tropsch synthesis has been suggested for the production of DMAA and ketones.
Databáze:	OpenAIRE
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