Study of radiation-induced grafting of 2-hydroxyethyl methacrylate to chloroprene rubber membrane

Autor:	Fang Yue-E, Ma Chaoxiong, Ji Jun
Rok vydání:	1999
Předmět:	Radiation Chloroprene Scanning electron microscope Grafting Solvent chemistry.chemical_compound surgical procedures operative Monomer Membrane chemistry Natural rubber visual_art Polymer chemistry visual_art.visual_art_medium Copolymer Nuclear chemistry
Zdroj:	Radiation Physics and Chemistry. 54:159-163
ISSN:	0969-806X
Popis:	The radiation-induced grafting copolymerization of HEMA to chloroprene rubber membranes were studied by means of irradiation of cobalt-60 gamma ray. The structure and surface morphology of both grafted and ungrafted CR membranes were observed by FT-IR-PAS spectroscopy and scanning electron microscope (SEM), respectively. The experimental results showed that the change of the degree of grafting in a mixed solvent of water and ethanol is S-shaped curve. The degree of grafting increases with increasing pH values in grafting solution. The influences of dose, dose rate, monomer concentration and grafting temperature were investigated. The degree of grafting does not change with increasing membrane thickness. This result showed that the grafting of HEMA to CR membrane is surface grafting.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e9866141684b49499e8b93c5385bbbcb https://doi.org/10.1016/s0969-806x(98)00249-7 Zobrazit plný text záznamu Full Text from ScienceDirect