The Tian–Calvet calorimetry as a method for investigating heterogeneous hydrogenation catalysts based on IMC disperse powders
Autor: | E. A. Ganich, Semenenko Kirill N, N. A. Yakovleva |
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Rok vydání: | 2001 |
Předmět: |
Hydrogen
Metallurgy Intermetallic chemistry.chemical_element Calorimetry Atmospheric temperature range Condensed Matter Physics Catalysis Metal Matrix (chemical analysis) chemistry visual_art visual_art.visual_art_medium Physical chemistry Physical and Theoretical Chemistry Thermal analysis Instrumentation |
Zdroj: | Thermochimica Acta. 369:161-166 |
ISSN: | 0040-6031 |
DOI: | 10.1016/s0040-6031(00)00763-2 |
Popis: | The interaction of hydrogen with LaNi 3,5 Cu 1,5 — a catalyst for hydrogenation of organic compounds — was studied in a wide temperature range (308–373 K) by the Tian–Calvet differential heat-conduction calorimetry. The P – C – T -, Q – C – T -diagrams and the results of mathematical treatment of the calorimertic data are presented. The formation mechanism of active hydrogen solved in metal matrix is proposed. |
Databáze: | OpenAIRE |
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