Nonreactive interaction of methyl isocyanide and hydrogen chloride: isolation and characterization of CH3NC.cntdot..cntdot..cntdot.HCl in a pulsed jet

Autor:	Anthony C. Legon, D. G. Lister, H. E. Warner
Rok vydání:	1992
Předmět:	Hydrogen bond Methyl isocyanide Stereochemistry Isocyanide Dimer Rotational transition General Chemistry Biochemistry Catalysis Isotopomers chemistry.chemical_compound Colloid and Surface Chemistry chemistry Physical chemistry Rotational spectroscopy Hydrogen chloride
Zdroj:	Journal of the American Chemical Society. 114:8177-8180
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja00047a029
Popis:	The hydrogen-bonded dimer CH 3 NC...HCl has been isolated in a pulsed jet by keeping the reactive components CH 3 NC and HCl separate until the point at which they expand into the evacuated Fabry-Perot cavity of a pulsed nozzle Fourier-transform microwave spectrometer. The rotational spectra of the three symmetric-top isotopomers CH 3 NC...H 35 Cl, CH 3 NC...H 37 Cl, and CH 3 NC...D 35 Cl detected in this way have been analyzed to give the ground-state spectroscopic constants B 0 , D J , D JK , and χ (Cl)
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e95f63f530674d27e9e3627c02b1798a https://doi.org/10.1021/ja00047a029 Zobrazit plný text záznamu