Effects of swift heavy ions irradiation on polypyrrole thin films
Autor: | Fouran Singh, R. G. Sonkawade, R. C. Ramola, D.K. Avasthi, Subhash Chandra, J. M. S. Rana, S. Annapoorni, Abdullah Alqudami |
---|---|
Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Radiation Effects and Defects in Solids. 163:139-147 |
ISSN: | 1029-4953 1042-0150 |
Popis: | Conducting polypyrrole (PPY) polymer thin films, prepared by the electrochemical process, were irradiated with 50 MeV Li3+ and 90 MeV C6+ ions at different fluences, ranging from 1011 to 1014 ions cm−2. The structural and electrical properties of the swift heavy ions (SHI) irradiated films were analyzed using X-ray diffraction (XRD), Scanning electron microscope (SEM), and conductivity measurement methods. XRD analysis of SHI irradiated PPY films shows that the crystallinity of the PPY films increases with increasing fluences of lithium ions, but tends to become amorphous at higher fluence. Carbon ions irradiations lead to polymer destruction and simultaneous amorphization even at low fluence. The SEM studies of irradiated PPY films show systematic change in their surface morphologies. The surface was smoother at lower fluence but craters were observed at higher fluence. The surface conductivity of films increases with increasing fluence of lithium ions, which also turn to the virgin film conduct... |
Databáze: | OpenAIRE |
Externí odkaz: |