Formation of Chlorosilyl Pincer-Type Rhodium Complexes by Multiple Si–H Activations of Bis(phosphine)/Dihydrosilyl Ligands

Autor:	Daniel E. DeRosha, Alexander M. Deetz, Matthew T. Whited, Joseph W. Boerma, Daron E. Janzen
Rok vydání:	2014
Předmět:	Chemistry Metalation Ligand Organic Chemistry Cationic polymerization chemistry.chemical_element Photochemistry Medicinal chemistry Pincer movement Rhodium Inorganic Chemistry chemistry.chemical_compound Reactivity (chemistry) Physical and Theoretical Chemistry Trifluoromethanesulfonate Phosphine
Zdroj:	Organometallics. 33:5070-5073
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om5006319
Popis:	The synthesis and metalation of two bis(phosphine)/dihydrosilyl ligands at rhodium(I) sources is reported. Irrespective of the substitution at silicon (diaryl versus diamino), multiple Si–H activations and chloride migration afford tridentate bis(phosphine)/chlorosilyl complexes of Rh(I). For the diarylsilyl ligand, reaction with a cationic rhodium(I) triflate precursor gives the analogous triflatosilyl complex. The [P2Si]H2 proligands and their Rh complexes provide distinct opportunities for exploring metal/silicon cooperative reactivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e94d08761353c8a4892518f24d5e1dcf https://doi.org/10.1021/om5006319 Zobrazit plný text záznamu