Interaction of electron acceptors with bases—V

Autor:	Raymond K. Mackie, R. Foster
Rok vydání:	1962
Předmět:	chemistry.chemical_classification Ketone Sodium ethoxide Base (chemistry) Dinitrobenzene Organic Chemistry Electron acceptor Biochemistry Medicinal chemistry Solvent chemistry.chemical_compound chemistry Aqueous sodium hydroxide Drug Discovery Organic chemistry Conjugate
Zdroj:	Tetrahedron. 18:1131-1135
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)99278-6
Popis:	When m -dinitrobenzene in excess ketone as solvent is shaken with concentrated aqueous sodium hydroxide (The Janovsky reaction), the conjugate base of the ketone appears to form a σ-addition complex with the m -dinitrobenzene; whereas the product of interaction of m -dinitrobenzene with ketone in ethanolic sodium ethoxide (the Zimmermann reaction) is the conjugate base of the corresponding 2,4 dinitrobenzyl ketone.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e9439d295063c040487af6ddea942187 https://doi.org/10.1016/s0040-4020(01)99278-6 Zobrazit plný text záznamu