Oxidation of nickel thiolate ligands by dioxygen

Autor:	Michael J. Maroney, Roberta O. Day, Shaukat A. Mirza, Michelle A. Pressler, Manoj Kumar
Rok vydání:	1993
Předmět:	Reaction mechanism Ligand Stereochemistry Dithiol chemistry.chemical_element Crystal structure Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Nickel Reaction rate constant chemistry X-ray crystallography Molecule Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 32:977-987
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00058a038
Popis:	The reactions of Ni complexes of the tridentate dithiolate ligands RN(CH 2 CH 2 S - ) 2 and S(CH 2 CH 2 S - ) 2 with O 2 leading to the formation of complexes containing one S-hound sulfinate ligand are described. Reaction of the ligands with Ni(OAc) 2 yields dinuclear [Ni(L)] 2 complexes. Reaction of these dimers with Et 4 N(CN) yields Et 4 N + salts of the four-coordinate complex anions, [Ni(L)CN] - .
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e922a6de9e8c0f84a5caef12610688b2 https://doi.org/10.1021/ic00058a038 Zobrazit plný text záznamu