Structural, spectroscopic and catalytic properties of water-soluble hydride rhodium complexes [RhH(Rtpa+I−)4]H2O (R=Me, Et)
| Autor: | Florian P. Pruchnik, Piotr Smoleński, Zdzisław Gałdecki, Ewa Gałdecka |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
chemistry.chemical_classification
Hydride Iodide Inorganic chemistry Infrared spectroscopy chemistry.chemical_element Decane Crystal structure Medicinal chemistry Catalysis Rhodium Inorganic Chemistry chemistry.chemical_compound chemistry Materials Chemistry Proton NMR Physical and Theoretical Chemistry |
| Zdroj: | Inorganica Chimica Acta. 293:110-114 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/s0020-1693(99)00228-5 |
| Popis: | New rhodium(I) hydrido complexes [RhH(mtpa+I−)4]·H2O (1) and [RhH(etpa+I−)4]·H2O (2) (where mtpa+I−=1-methyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane iodide, etpa+I−=1-ethyl-1-azonia-3,5-diaza-7-phosphatricyclo[3.3.1.13,7]decane iodide) have been synthesized and characterized using 1H, 31P NMR and IR spectra and X-ray crystallography. Both complexes have the trigonal-bipyramidal structure. The 1H NMR spectra indicate that in solutions the complexes have fluxional properties. The compounds are very stable in water under neutral atmosphere. They are efficient catalysts of hydrogenation of CC bonds in two-phase catalytic systems. |
| Databáze: | OpenAIRE |
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