Cerium-Containing Hydroxyapatites with Luminescent Properties
Autor: | Vladimir S. Komlev, S. M. Barinov, Sergey Kozyukhin, Yu. O. Nikitina, A. Yu. Demina, A. S. Lysenkov, N. V. Petrakova |
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Rok vydání: | 2021 |
Předmět: | |
Zdroj: | Russian Journal of Inorganic Chemistry. 66:1067-1072 |
ISSN: | 1531-8613 0036-0236 |
Popis: | Powders of cerium-containing hydroxyapatites (Ce–HA) with an estimated cerium concentration of up to 0.5 mol % have been synthesized. The phase formation and luminescent properties of the compounds after heat treatment in oxidizing and reducing atmospheres have been investigated. It has been shown that a high HA luminescence intensity can be achieved by preventing the cerium(III) → cerium(IV) transition in a reducing atmosphere at 900–1200°C, as well as by cosubstitution of Ce3+ and Li+ ions for Ca2+ ions to compensate for the excess charge of the additive. The dependence of the luminescence intensity of materials on the heat treatment temperature and cerium concentration is shown. |
Databáze: | OpenAIRE |
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