Construction of cyclopentane-fused coumarins via DBU-catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes

Autor:	Xiaoqun Cao, Chunhao Yuan, Jing Gu, Huimin Yang, Biming Mao, Yanqing Ge, Shan Luo, Huawei Lin, Qi Gong
Rok vydání:	2021
Předmět:	chemistry.chemical_compound 010405 organic chemistry Chemistry General Chemical Engineering Organic chemistry General Chemistry Chemoselectivity 010402 general chemistry Cyclopentane 01 natural sciences Cycloaddition 0104 chemical sciences Catalysis
Zdroj:	RSC Advances. 11:20118-20122
ISSN:	2046-2069
Popis:	The metal-free DBU catalyzed [3+2] cycloaddition of 3-homoacyl coumarins with cyclic 1-azadienes proceeded smoothly to furnish the corresponding highly functionalized cyclopentane-fused coumarins with excellent diastereoselectivity and complete chemoselectivity and in good yields under mild conditions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e903fcaed7bbeb653ff1584c4c5f243b https://doi.org/10.1039/d1ra03387e Zobrazit plný text záznamu