Crystal structure of Co(III) α-dimethylglyoximates with imidazole
| Autor: | P. N. Bourosh, E. B. Coropceanu, A. A. Vitiu |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Substitution reaction
Infrared spectroscopy Ionic bonding Crystal structure 010402 general chemistry 010403 inorganic & nuclear chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound Crystallography Dimethylglyoxime chemistry Materials Chemistry Imidazole Molecule Physical and Theoretical Chemistry Single crystal |
| Zdroj: | Journal of Structural Chemistry. 58:526-531 |
| ISSN: | 1573-8779 0022-4766 |
| DOI: | 10.1134/s0022476617030131 |
| Popis: | Two new dimethylglyoximate complexes [Co(DmgH)2(Im)Cl] (I) and (ImH)[Co(DmgH2)2Cl2] (II), where DmgH− is the dimethylglyoxime residue and Im is the imidazole molecule, are synthesized. The composition and structure of the crystals are determined from the elemental analysis, IR spectra, and single crystal X-ray diffraction. Complex I is molecular, containing the Im molecule as a coordinated ligand; complex II is of the ionic type with (ImH)+ involved as an outer-sphere organic cation. The mode of component packing in the crystals mainly depends on the imidazole position in the compounds. |
| Databáze: | OpenAIRE |
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