Self-Assembly of Two Novel Cadmium(II) Complexes: One from Tripodal Imine−Phenol Ligand and the Other from In situ Partial Degradation of Dipolar Imine−Phenol Ligand

Autor:	Li Chen, Qing-Guang Zhan, Zheng-Yuan Zhou, Shi-Zheng Zhu, Yue-Peng Cai, Xiu-Xia Zhou, Mao-Sheng Liu
Rok vydání:	2008
Předmět:	Schiff base Stereochemistry Ligand Coordination number Imine General Chemistry Condensed Matter Physics chemistry.chemical_compound Hydrolysis chemistry Polymer chemistry General Materials Science Amine gas treating Chemical stability Group 2 organometallic chemistry
Zdroj:	Crystal Growth & Design. 8:2076-2079
ISSN:	1528-7505 1528-7483
Popis:	Through different synthetic strategies, two novel cadmium(II) complexes have been synthesized and characterized. The first mesocate complex Cd3L12 (1) with S6 symmetry based on tris[(2-salicylaldeneimino)ethyl]-amine (H3L1 or H3trensal) is constructed from the self-assembly of Cd2+ ion and two chiral building block units, Δ- and Λ-[Cd(trensal)]−, in which the coordination numbers of six and seven for Cd(II) ions are rarely found in one discrete compound without any auxiliary ligand. However, under the same reaction conditions, CdL3(H2O)(NO3) (2) with N3O4 donors is obtained from CdII coordination induced partial hydrolysis of dipolar imine−phenol Schiff base ligand N,N′-bis(salicylidene)-3, 6-dioxa-1,8-diaminooctane (H2L2), which provides the first example of hydrated CdII salt promoting partial degradation of the imine−phenol ligand. The strong fluorescence emission of 1 makes it a potentially useful photoactive material for its high thermal and chemical stability.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e8e289d74f5bd3ec202ba437c12386e9 https://doi.org/10.1021/cg8002228 Zobrazit plný text záznamu