The 1,5-bisdehydro[12]annulenyl and 1,5,9-tridehydro[12]annulenyl radical anions and dianions

Autor:	N. E. Rowland, F. Sondheimer, Peter J. Garratt
Rok vydání:	1971
Předmět:	Chemistry Potassium Organic Chemistry Drug Discovery chemistry.chemical_element Annulene Photochemistry Biochemistry Ion
Zdroj:	Tetrahedron. 27:3157-3162
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)98108-6
Popis:	The reduction of 1,5-bisdehydro[12]annulene ( 1 ) and 1,5,9-tridehydro[12]annulene ( 4 ) with potassium proceeds by a one electron addition to give the corresponding 1,5-bisdehydro[12]annulenyl and 1,5,9-tridehydro[12]annulenyl radical anions ( 2,5 ), Further reduction converts the radical anions into the 1,5-bisdehydro[12]annulenyl and 1,5,9-tridehydro[12]annulenyl dianions ( 3, 6 ). The properties of these ions are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e8cd778e192a42c396409bb643008ce0 https://doi.org/10.1016/s0040-4020(01)98108-6 Zobrazit plný text záznamu