Porosity and Guest Inclusion in Cyclobenzoin Esters

Autor: Christina R. Stegemoller, Mohamed I. Hashim, Corie McHale, Xiqu Wang, Ognjen Š. Miljanić
Rok vydání: 2019
Předmět:
Zdroj: Crystal Growth & Design. 19:562-567
ISSN: 1528-7505
1528-7483
DOI: 10.1021/acs.cgd.8b01774
Popis: Cyclotetrabenzoin esters form porous solid-state structures with infinite one-dimensional channels and a Brunauer–Emmett–Teller surface area of ∼570 m2 g–1. Their assembly appears not to involve any strong covalent or noncovalent bonds between individual molecules. The isobutyric ester of cyclotetrabenzoin includes molecules of CS2 within its central cavity in an arrangement resembling an insulated wire.
Databáze: OpenAIRE