Molybdenum binding site models for the molybdenum cofactor. Synthesis, spectroscopic characterization, and EHMO analysis of (NBun4)Na[Mo(O2CC(S)Ph2)3]

Autor:	Antonio Cervilla, José A. Ramírez, Pedro Palanca, Elisa Llopis
Rok vydání:	1993
Předmět:	biology Inorganic chemistry Active site Crystal structure Cofactor Inorganic Chemistry chemistry.chemical_compound Crystallography Monomer chemistry Enzyme model biology.protein Molecule Carboxylate Physical and Theoretical Chemistry Molybdenum cofactor
Zdroj:	Inorganic Chemistry. 32:2085-2091
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00062a034
Popis:	The reaction of the cis-dioxo Mo(VI) complex [MoO 2 (O 2 CC(S)Ph 2 ) 2 ] 2- (1), having two coordinated thiobenzilate ligands, with an excess of thiobenzilic acid yields the monomeric monooxo Mo(V) complex [MoO(O 2 CC(S)Ph 2 ) 2 ] - (2), which is stable under these acidic conditions. However, partial neutralization of the thiobenzilic acid results in the reduction of 2, which, once formed.
Databáze:	OpenAIRE
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