Structural study of the copper(II)–enrofloxacin metallo-antibiotic
| Autor: | Emmanuel Guillon, Isabelle Déchamps-Olivier, Stéphanie Boudesocque, Stéphanie Sayen, Hussein Ftouni |
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| Rok vydání: | 2012 |
| Předmět: |
X-ray absorption spectroscopy
Absorption spectroscopy Extended X-ray absorption fine structure Chemistry chemistry.chemical_element Copper XANES law.invention Inorganic Chemistry Crystallography Octahedron law Materials Chemistry Physical and Theoretical Chemistry Absorption (chemistry) Electron paramagnetic resonance |
| Zdroj: | Inorganica Chimica Acta. 382:186-190 |
| ISSN: | 0020-1693 |
| Popis: | The structure of [Cu(erx)2(H2O)2] complex was assessed using copper K-edge X-ray absorption spectroscopy (XAS) through X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) combined with EPR spectroscopy. A Jahn–Teller distorted octahedra was evidenced for Cu2+ geometry. Four equatorial oxygen atoms from two enrofloxacin ligands were found with Cu–Oeq distances of 1.93 A (±0.02). The coordination was completed by two water molecules in axial position at an average distance of 2.11 A. |
| Databáze: | OpenAIRE |
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