Novel hydrazone moieties containing polymers for optoelectronics

Autor:	J.V. Grazulevicius, Zbigniew Tokarski, Vytautas Getautis, Maryte Daskeviciene, Vygintas Jankauskas, Tadas Malinauskas, Valentas Gaidelis
Rok vydání:	2006
Předmět:	chemistry.chemical_classification General Chemical Engineering General Physics and Astronomy Hydrazone General Chemistry Polymer Photochemistry Triphenylamine Catalysis Time of flight chemistry.chemical_compound Differential scanning calorimetry chemistry Ionization Polymer chemistry Triethylamine
Zdroj:	Journal of Photochemistry and Photobiology A: Chemistry. 180:23-27
ISSN:	1010-6030
DOI:	10.1016/j.jphotochem.2005.09.010
Popis:	The novel family of hole transporting polymers containing hydrazone moieties is reported. The polymers were prepared in polyaddition reaction of hydrazone-containing diepoxydes with 2,5-dimercapto-1,3,4-thiadiazole in the presence of catalyst triethylamine (TEA). Obtained polymers were found to constitute novel polymeric hole transporting materials (TM) characterized by differential scanning calorimetry (DSC) and time of flight method. The highest hole-drift mobility in the newly synthesized polymers exceed 10 −5 cm 2 V −1 s −1 at an electric field of 10 6 V cm −1 was observed in the TM with triphenylamine moieties. The electron photoemission spectra of the obtained polymers have been recorded and the ionization potentials of 5.24–5.33 eV have been determined.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e896805a26cf5aa7dd92db7a1f980538 https://doi.org/10.1016/j.jphotochem.2005.09.010 Zobrazit plný text záznamu Full Text from ScienceDirect