In-situ elevated-temperature TEM study of (AgSbTe2)15(GeTe)85

Autor: Xuezheng Wei, Matthew J. Kramer, J. L. Harringa, Bruce A. Cook
Rok vydání: 2007
Předmět:
Zdroj: Journal of Materials Science. 42:7643-7646
ISSN: 1573-4803
0022-2461
DOI: 10.1007/s10853-007-1898-x
Popis: (AgSbTe2)15(GeTe)85 (TAGS-85) is a p-type semiconductor characterized by a maximum dimensionless thermoelectric figure of merit of 1.4–1.7 at elevated temperature. In this study, the microstructure of as-solidified TAGS-85 at room temperature and elevated temperature (160 °C) was investigated using TEM. At room temperature, pervasive twinning was observed throughout the specimen. Upon heating to above 120 °C, some of the twins dissolved and new point defects began to nucleate. The mechanisms responsible for formation of high temperature defects are discussed.
Databáze: OpenAIRE