Discovery of an olivine-type lithium manganese thiophosphate, LiMnPS4, via a building block approach
| Autor: | Amitava Choudhury, Aleksandr V. Chernatynskiy, Srikanth Balijapelly, Kartik Ghosh |
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| Rok vydání: | 2021 |
| Předmět: |
Materials science
Band gap Metals and Alloys chemistry.chemical_element General Chemistry Manganese Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Thiophosphate chemistry.chemical_compound chemistry Ferromagnetism Materials Chemistry Ceramics and Composites Physical chemistry Lithium Diffuse reflection Ternary operation Metamagnetism |
| Zdroj: | Chemical Communications. 57:13182-13185 |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | An olivine-type orthothiophospate LiMnPS4 has been synthesized for the first time through a building block approach by reacting preformed ternary lithium thiophospate with MnCl2. Diffuse reflectance measurements show an optical band gap of 2.36 eV, which is further confirmed by DFT calculations. Irreversible weak ferromagnetic ordering and metamagnetism are verified through preliminary magnetic measurements. |
| Databáze: | OpenAIRE |
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