An Aluminum Complex Supported by a Fluorous Diamino-Dialkoxide Ligand for the Highly Productive Ring-Opening Polymerization of ε-Caprolactone

Autor:	Richard Welter, Christophe M. Thomas, Jean-François Carpentier, Samuel Dagorne, Yun Chi, Abderramane Amgoune, Laurent Lavanant
Rok vydání:	2005
Předmět:	Aluminum Complex Ligand Organic Chemistry Ring-opening polymerization Inorganic Chemistry chemistry.chemical_compound chemistry Polymerization Polymer chemistry Alkoxide High activity Physical and Theoretical Chemistry Caprolactone Dichloromethane
Zdroj:	Organometallics. 24:6279-6282
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om050512s
Popis:	The new discrete aluminum alkoxide complex (iPrO)Al{CH2NMeCH2C(CF3)2O}2 (1) initiates the controlled ring-opening polymerization of caprolactone in dichloromethane at 20 °C with high activity (TOF ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e840b33e1fe792dc2ff39af1bb2e44cb https://doi.org/10.1021/om050512s Zobrazit plný text záznamu