Synthesis, Characterization and Antimicrobial Activities of Ni(II), Cu(II), Zn(II) and Cd(II) Ternary Complexes Involving 8-Quinolinol as Primary Ligand and Bidentate Glycine or Tridentate Aspartic Acid as Secondary Ligand

Autor:	V. M. Patel, J. D. Joshi, Jabali Vora, A. K. Patel, Sangita Sharma, Rasmikant A. Patel
Rok vydání:	1999
Předmět:	Denticity Chemistry Stereochemistry Ligand Infrared spectroscopy Medicinal chemistry Inorganic Chemistry Metal Paramagnetism Octahedron visual_art Aspartic acid visual_art.visual_art_medium Chelation Physical and Theoretical Chemistry
Zdroj:	Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 29:193-203
ISSN:	1532-2440 0094-5714
DOI:	10.1080/00945719909349443
Popis:	This paper reports the isolation of mixed ligand complexes of the type MAL, where M = Ni(II), Cu(II), Zn(II), Cd(II) A = 8-quinolinol(HQUIN) and L = amino acid (glycine-HL' or aspartic acid-H2L'). The complexes of Ni(II) and Cu(II) are coloured and insoluble in common organic solvents. Their structures have been elucidated on the basis of magnetic, electronic and IR spectroscopy. Electronic spectra, in conjunction with magnetic moments, are in accord with an octahedral environment around the central metal ion in all metal chelates except the Zn(II) and Cd(II) chelates. All chelates are paramagnetic except the Zn(II) and Cd(II) compounds which are found to be diamagnetic. A study of the thermal properties and antimicrobial activity of the complexes has also been carried out.
Databáze:	OpenAIRE
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