Carbonization of coals to produce anisotropic cokes. 2. Up-grading of modification activities of petroleum process residues and their correlation with structural parameters
| Autor: | Yozo Korai, Kenjiro Takeshita, Isao Mochida, Hideichi Matsuoka, Hiroshi Fujitsu |
|---|---|
| Rok vydání: | 1982 |
| Předmět: |
Aluminium chloride
Carbonization Chemistry General Chemical Engineering Organic Chemistry technology industry and agriculture Energy Engineering and Power Technology Aromaticity Coke Alkylation Condensation reaction Ring (chemistry) complex mixtures Fuel Technology Yield (chemistry) medicine Organic chemistry medicine.drug |
| Zdroj: | Fuel. 61:595-602 |
| ISSN: | 0016-2361 |
| DOI: | 10.1016/0016-2361(82)90003-5 |
| Popis: | Modifying activities of petroleum pitches and up-graded pitches in the co-carbonization with a range of coals have been examined with the object of proposing an effective co-carbonization process for blast-furnace coke production. Up-grading of additives was attempted using thermal, acidic and oxidative reactions. Acidic reactions with aluminium chloride were most effective with lighter petroleum residues of initially poor modifying activity, this being attributed to dealkylation, ring-closure and ring condensation reactions. The relation between modifying activity and structural indices is discussed. The aromaticity ( f a ) and the naphthenic ring number in the unit structure T n , us can be used as appropriate parameters for the activity when the coking yield is taken into account. |
| Databáze: | OpenAIRE |
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