Dynamic scaling in colloid aggregation reaction limited process induced by electrolytes and polyelectrolytes

Autor: C. Graillat, J. Widmaier, R. Varoqui, Emile Pefferkorn
Rok vydání: 2007
Předmět:
Zdroj: Trends in Colloid and Interface Science IV ISBN: 9783798508392
DOI: 10.1007/bfb0115546
Popis: We have studied the irreversible aggregation of colloidal polystyrene spheres using a particle counter technique. The mode of cluster growth is found to be modelled by a reaction limited aggregation process. Elementary grains disappear by collision with larger aggregates, which, in return, are only slowly formed. This complex process has one important characteristic: at each time, the concentration of small aggregates of g elementary grains scales like g −τ, τ being a universal exponent in reaction limited processes.
Databáze: OpenAIRE