Fine Structure of the Glass Transition in Amorphous Polymers: Slight Shoulder in the Shear H Spectrum at the L Peak
| Autor: | S. Reissig, E. Donth, K. Schröter, S. Vieweg, Mario Beiner |
|---|---|
| Rok vydání: | 1996 |
| Předmět: |
chemistry.chemical_classification
Materials science Polymers and Plastics Organic Chemistry Vulcanization Analytical chemistry Polymer law.invention Amorphous solid Inorganic Chemistry Shear modulus chemistry.chemical_compound chemistry Natural rubber law visual_art Polymer chemistry Materials Chemistry Vinyl acetate visual_art.visual_art_medium Polystyrene Glass transition |
| Zdroj: | Macromolecules. 29:3996-3999 |
| ISSN: | 1520-5835 0024-9297 |
| DOI: | 10.1021/ma951346a |
| Popis: | A slight shoulder in the shear relaxation spectrum (H) at the relaxation time for the main maximum of the retardation spectrum (L) was detected for three amorphous polymers : polystyrene, poly(vinyl acetate), and a slightly vulcanized natural rubber. This finding is discussed in terms of a distinctive manifestation of different molecular modes across the glass (main) transition. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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