Reactions of Organic Compounds with Higher Fluorides off- andd-Elements in Groups V and VI

Autor:	V T Orekhov
Rok vydání:	1977
Předmět:	Substitution reaction chemistry Phosphorus Inorganic chemistry chemistry.chemical_element General Chemistry Nitrogen Medicinal chemistry Lone pair Redox Sulfur Oxygen Adduct
Zdroj:	Russian Chemical Reviews. 46:420-435
ISSN:	1468-4837 0036-021X
Popis:	The interaction of higher fluorides of f- and d-elements in Groups V and VI of the Periodic System with alkanes, alkenes, aromatic compounds, and also hetero-organic derivatives containing silicon, nitrogen, phosphorus, oxygen, and sulphur is surveyed. The relative oxidising powers of the inorganic fluorides are assessed. Organic donors possessing lone pairs of electrons form with penta- and hexa-fluorides of low oxidising power relatively stable adducts, least stable with the hexa-fluorides. Highly active inorganic fluorides undergo with organic compounds redox and substitution reactions, yielding complicated mixtures of metal-containing and fluorinated organic substances. A list of 169 references is included.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::e7b25a1b07650bded85bd8a8dcd9247d https://doi.org/10.1070/rc1977v046n05abeh002144 Zobrazit plný text záznamu